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Modeling of the Valence Tautomeric Transformation in Heterometallic [Cr-dhbq-Co] Molecules
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| dc.contributor.author | ROMAN, M. A. | |
| dc.contributor.author | KLOKISHNER, S. I. | |
| dc.date.accessioned | 2020-05-27T18:22:15Z | |
| dc.date.available | 2020-05-27T18:22:15Z | |
| dc.date.issued | 2019 | |
| dc.identifier.citation | ROMAN, M. A., KLOKISHNER, S. I. Modeling of the Valence Tautomeric Transformation in Heterometallic [Cr-dhbq-Co] Molecules. In: ICNMBE-2019: International conference on Nanotechnologies and Biomedical Engineering: proc. of the 4rd intern. conf., Sept. 18-21, 2019: Program and Abstract Book. Chişinău, 2019, p. 75. ISBN 978-9975-72-392-3. | en_US |
| dc.identifier.isbn | 978-9975-72-392-3 | |
| dc.identifier.uri | http://repository.utm.md/handle/5014/8417 | |
| dc.identifier.uri | https://doi.org/10.1007/978-3-030-31866-6_14 | |
| dc.description | Access full text - https://doi.org/10.1007/978-3-030-31866-6_14 | en_US |
| dc.description.abstract | In the present communication we report a model that describes the valence tautomeric transformation in a crystal consisting of heterometallic [Cr-dhbq-Co] molecules. The model takes into account the states arising from two different configurations of the molecule, namely, Cr3+-dhsq3−-Co3+ and Cr3+-dhsq2−-Co2+, the Heisenberg exchange interaction between the dhsq3− ligand and the Cr3+ ion as well as the cooperative electron-deformational and dipole-dipole interactions. The problem is solved in the mean field approximation. The main peculiarities of the valence tautomeric transformation are elucidated. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Tehnica UTM | en_US |
| dc.rights | Attribution-NonCommercial-NoDerivs 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/us/ | * |
| dc.subject | heterometallic molecules | en_US |
| dc.subject | valence tautomeric transformation | en_US |
| dc.title | Modeling of the Valence Tautomeric Transformation in Heterometallic [Cr-dhbq-Co] Molecules | en_US |
| dc.type | Article | en_US |
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