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Modeling of the Valence Tautomeric Transformation in Heterometallic [Cr-dhbq-Co] Molecules

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dc.contributor.author ROMAN, M. A.
dc.contributor.author KLOKISHNER, S. I.
dc.date.accessioned 2020-05-27T18:22:15Z
dc.date.available 2020-05-27T18:22:15Z
dc.date.issued 2019
dc.identifier.citation ROMAN, M. A., KLOKISHNER, S. I. Modeling of the Valence Tautomeric Transformation in Heterometallic [Cr-dhbq-Co] Molecules. In: ICNMBE-2019: International conference on Nanotechnologies and Biomedical Engineering: proc. of the 4rd intern. conf., Sept. 18-21, 2019: Program and Abstract Book. Chişinău, 2019, p. 75. ISBN 978-9975-72-392-3. en_US
dc.identifier.isbn 978-9975-72-392-3
dc.identifier.uri http://repository.utm.md/handle/5014/8417
dc.identifier.uri https://doi.org/10.1007/978-3-030-31866-6_14
dc.description Access full text - https://doi.org/10.1007/978-3-030-31866-6_14 en_US
dc.description.abstract In the present communication we report a model that describes the valence tautomeric transformation in a crystal consisting of heterometallic [Cr-dhbq-Co] molecules. The model takes into account the states arising from two different configurations of the molecule, namely, Cr3+-dhsq3−-Co3+ and Cr3+-dhsq2−-Co2+, the Heisenberg exchange interaction between the dhsq3− ligand and the Cr3+ ion as well as the cooperative electron-deformational and dipole-dipole interactions. The problem is solved in the mean field approximation. The main peculiarities of the valence tautomeric transformation are elucidated. en_US
dc.language.iso en en_US
dc.publisher Tehnica UTM en_US
dc.rights Attribution-NonCommercial-NoDerivs 3.0 United States *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/us/ *
dc.subject heterometallic molecules en_US
dc.subject valence tautomeric transformation en_US
dc.title Modeling of the Valence Tautomeric Transformation in Heterometallic [Cr-dhbq-Co] Molecules en_US
dc.type Article en_US


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