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Raman scattering study of pressure-induced phase transitions in AIIB2IIIC4VI defect chalcopyrites and spinels

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dc.contributor.author TIGINYANU, I. M.
dc.contributor.author URSAKI, V. V.
dc.contributor.author MANJÓN, F. J.
dc.contributor.author TEZLEVAN, V. E.
dc.date.accessioned 2020-10-09T08:46:31Z
dc.date.available 2020-10-09T08:46:31Z
dc.date.issued 2003
dc.identifier.citation TIGINYANU, I. M., URSAKI, V. V., MANJÓN, F. J. et al. Raman scattering study of pressure-induced phase transitions in AIIB2IIIC4VI defect chalcopyrites and spinels. In: Journal of Physics and Chemistry of Solids. 2003, V. 64, Nr. 9, pp. 1603 - 1607. ISSN 0022-3697. en_US
dc.identifier.uri https://doi.org/10.1016/S0022-3697(03)00098-2
dc.identifier.uri http://repository.utm.md/handle/5014/10608
dc.description Access full text - https://doi.org/10.1016/S0022-3697(03)00098-2 en_US
dc.description.abstract AIIB2IIIC4VI defect chalcopyrites (DC) and spinels were investigated by Raman scattering spectroscopy under hydrostatic pressure up to 20 GPa. All these compounds were found to undergo a phase transition to a Raman inactive defect NaCl-type structure. The phase transition is reversible for spinels and irreversible for DC. From the analysis of the pressure behavior of Raman-active modes, it was concluded that the phase transition from spinel to NaCl-type structure is direct in MnIn2S4 and CdIn2S4, while it occurs via an intermediate LiVO2-type NaCl superstructure in MgIn2S4. The observed differences in the pressures and the paths of the pressure-induced phase transitions in AIIB2IIIC4VI compounds are discussed. en_US
dc.language.iso en en_US
dc.publisher ELSEVIER en_US
dc.rights Attribution-NonCommercial-NoDerivs 3.0 United States *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/us/ *
dc.subject semiconductors en_US
dc.subject phase transitions en_US
dc.subject high pressure en_US
dc.title Raman scattering study of pressure-induced phase transitions in AIIB2IIIC4VI defect chalcopyrites and spinels en_US
dc.type Article en_US


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